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Q.

Arrange the aqueous solutions of A(0.01 M sodium chloride), B(0.01 M glucose) and C(0.01 M acetic acid) in increasing order of boiling points.

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a

A>B>C

b

A>C>B

c

B>A>C

d

B>C>A

answer is B.

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Detailed Solution

ΔTb=Kbm, larger the molality ( or concentration for dilute solution), larger the value of ΔTb.Hence, larger will be the boiling point. Though, all the three solutions are equimolar, but the number of species available ( or the total concentration of species) will follow the order A> C > B. The same order holds good for boiling points.

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