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Q.

Arrange the following alkenes in order of decreasing stability

1) 1-pentene

2) Cis-2-pentene

3) Trans-2- pentene

4) 2-methyl-2-pentene

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a

1 > 2 > 3 > 4

b

4 > 3 > 2 > 1

c

1 > 3 > 4 > 2

d

3 > 4 > 1 > 2

answer is B.

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Detailed Solution

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1) has 2 α-hydrogens, 2) and 3) have 5 α-hydrogens each while 4) has 8 α-hydrogens. More the number of α-hydrogens, more will be the number of hyperconjugative structures and more will be the stability. Moreover, trans isomer is more stable than cis isomer on account of steric hindrance.

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