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Q.

Arrange the following alkyl halides in decreasing order of the rate of  -elimination reaction with alcoholic KOH

i) (CH3)2CHCH2Br

 ii) CH3CH2Br

 iii) CH3CH2CH2Br

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a

(i)>(ii)>(iii)

b

(iii)>(ii)>(i)

c

(i)>(iii)>(ii)

d

(ii)>(iii)>(i)

answer is D.

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Detailed Solution

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Stability of alkene after β-elimination directly depends on the number of β-substituents.

Since number of β- methyl substituent in (i) is 2, (iii) is 1 and (ii) is 0, thus the correct order of stability is: (i)>(iii)>(ii).

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