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Q.

Arrange the following  amines in the decreasing order of basicity :
Question Image

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a

III>I>II

b

I>II>III

c

III>II>I

d

I>III>II

answer is B.

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Detailed Solution

Compound ,III Question Image  is most basic as the lone pair of nitrogen is easily available for the donation 
In case of compound Question Image lone pair is not involved in resonance but nitrogen atom is Question Image  hybridsed, whereas in compound II the lone pair of nitrogen is involved in aromaticity which makes it least basic. 

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