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Q.

Arrange the following carbanions in decreasing order of stability

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a

IV > III > I > II

b

I > II > IV > III

c

IV > III > II > I

d

II > I >III > IV

answer is D.

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Detailed Solution

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In I and II -sp-hybridized carbon atom is more electronegative than sp3
-hybridized carbon atom and hence, can accommodate the negative charge more effectively.

 −CH3 group has +I effect, therefore, it means decrease in the negative charge and hence, destabilises the carbanion.

The order of EN is sp>sp2>sp3.
.

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