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Q.

Arrange the following compounds in the increasing order of homolytic (C-C) bond dissociation energy.
I. Propane
II. Ethane
III. 2,2-Dimethyl propane
IV. 2-Methyl propane

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a

(II) < (I) < (IV) < (III)

b

(III) < (IV) < (II) < (I)

c

(I) < (III) < (II) < (IV)

d

(III) < (IV) < (I) < (II)

answer is C.

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Detailed Solution

If the carbon is connected to more electron rich groups then the C-C bond cleavage becomes difficult due to high electron density.

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