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Q.

Arrange the following gases in increasing order of vander Waals constant ‘a’
(A) Ar, (B) CH4, (C) H2O, (D) C6H6
Choose the correct option from the following

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a

C, D, B and A

b

B, C, D and A

c

A, B, C and D

d

D, C, B and A

answer is C.

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Detailed Solution

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With increasing size, molecular interactions, increases, hence ‘a’ also increase

Vanderwaal constant – ‘a’  (i) Ar = 1.34  (ii) CH4 = 2.25  (iii) H2O = 5.46  (iv) C6H6 = 18.57

  ‘a’ symbolises force of attraction and directly proportional to surface area

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