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Q.

Arrange the following groups in order of decreasing − − R (or) M

1)-NO2 

 2)-SO3H 

 3)-CF3 

 4)-CHO

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a

1>4>3>2

b

1>2>4>3

c

4>3>2>1

d

1>3>2>4

answer is B.

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Detailed Solution

Mesomeric effect, -R or –M effect groups withdraw the π electrons from the rest part of the molecule. Thus, -M effect can be compared based on electro negativity. Decreasing order of –R (or) –M effect of groups is

-NO2  >-SO3H  >-CHO >-CF3 

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