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Q.

Arrange the following in decreasing order of reactivity towards EAS (electrophilic aromatic substitution)

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a

a>b>c

b

c>b>a

c

a>c>b

d

c>a>b

answer is A.

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Detailed Solution

-CH3 > -CD3 > -CT3
Order of hyperconjugation on the basis of bond energy.
Strong bond means less hyperconjugation.

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