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Q.

Arrange the following in increasing order of boiling points:
CH33N,C2H5OH,C2H5NH2

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Detailed Solution

The increasing order of boiling point is C2H5OH > C2H5NH2 > (CH3)3N. N−H···N hydrogen bond is weaker than an O−H···O hydrogen bond, because the difference in electronegativity between nitrogen and hydrogen (3.0–2.1 = 0.9) is less than that between oxygen and hydrogen (3.5–2.1 = 1.4).

The boiling point order is as follows:
CH33N<C2H5NH2<C2H5OH

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