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Q.

Arrange the following in order of C-Br bond strength in polar solvent.

I) Question Image             II) Question Image         III) Question Image     IV) Question Image

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a

IV < III < II < I

b

III < IV < I < II

c

II < I < III < IV

d

I < II < III < IV

answer is A.

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Detailed Solution

Easy of breaking of C – Br bond depends upon the stability of carbocation.

 

Question Image

As strength of C – Br  bond increases, breaking of C – Br  bond becomes difficult.

Hence, The order of C – Br  Bond Strength

I   <     II      <       III     <        IV

 

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