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Q.

Arrange the following in order of decreasing N-O bond length NO2+NO2- and NO3-

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a

NO2->NO3>  -NO2++

b

NO2+>NO3->NO2-

c

NO3->NO2+>NO2-

d

NO3->NO2->NO2+

answer is B.

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Detailed Solution

N atom in NO2+  is sp hybridized whereas in NO2- and NO3-, it is sp2 hybridized.

Bond order = No.of bond between two atoms in all possible structuresNo. of resonating structures

Bond order of NO2+ = 2

Bond order of NO2- :

Question Image
B.O = 2+12=1.5

Bond order of NO3- :

Question Image
 B.O = 2+1+13=1.33

Since Bond length 1Bond order

So order of bond length is, NO3->NO2->NO2+

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