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Q.

Arrange the following in order of increasing mass 

(i) 3.0115  ×  1023 molecules of white phosphorus

(ii) 10 moles of H2 gas

(iii) 1 g molecule of anhydrous Na2CO3

(iv) 33.6 L of CO2 gas at STP

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a

ii < i < iv < iii

b

iii > iv > i > ii

c

i < ii < iv < iii

d

i < iv < iii < ii

answer is A.

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Detailed Solution

(i) At. wt. of P = 31 and atomicity of P is 4

Mol. wt.of white P = 31 x 4 = 124

  6.023  ×  1023molecules  ofwhite  P  weigh  124g  3.0115  ×  1023molecules  ofwhite  P  weigh  1246.023×3.015=62g ii  Wt.  of  1  mole  ofH2gas=2gWt.  of  10  moles  of  H2gas=2×10=20giii1g  molecule  ofanhydrous  Na2CO3=Mol  wt.  of  Na2CO3                                                                             in  g=106  givAtSTP  22.4  L  CO2weighs  44  g   33.6  L  CO2  weighs  4422.4×  33.6  g                                           =66  gSo,  the  correct  choice   ii<  i<  iv<  iii

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