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Q.

Arrange the following in the order of their reactivity of ${S_{N}}^{2}$ reaction
(i) (ii)
(iii) $C H_{2} = C H - C H_{2} C l$ (iv) $C H_{3} C H_{2} C H_{2} C l$

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a

$i i > i > i i i > i v$

b

$i v > i i i > i > i i$

c

$i > i i > i v > i i i$

d

$i > i i i > i v > i i$

answer is A.

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Detailed Solution

Reactivity $\propto$ stability of Transition State.

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Arrange the following in the order of their reactivity of SN2 reaction (i) (ii) (iii) CH2=CH−CH2Cl (iv) CH3CH2CH2Cl