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Q.

Arrange the following ions in the decreasing order of their size’s

Be+,Cl-,S-2,Na+,Mg+2,Br-.

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a

Be+2>Mg+2>Na+<S-2Br-<Cl-

b

Be+2<Mg+2<Na+<S-2<Br-<Cl-

c

Br->S-2>Cl>Na+>Mg+2>Be+2

d

None of these

answer is C.

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Detailed Solution

By loss or gain of electrons by an atom the atomic radius is changed.

Be+2(He)1st periods 

Na+,Mg+2(Ne)2nd periods

Cl-,S-2(Ar)3rd periods

Br-(Br)4th periods

In isoelectronic species, for cations if nuclear charge (+ve) increases and then size decreases, for anions if  the negative charge (-Ve) increases and then size increases.  The size of ions increasing order in different periods as per their electronic configuration is shown below

Br->S-2>Cl>Na+>Mg+2>Be+2

 

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