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Q.

Arrange the following metal complex/compounds in the increasing order of spin only magnetic moment. Presume all the three, high spin system. (Atomic numbers Ce=58, Gd=64 and Eu=63)

a) (NH4)2[Ce(NO3)6]        b) Gd(NO3)3        c) Eu(NO3)3    answer is       

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a

a<b<c

b

b<a<c

c

c<a<b

d

a<c<b

answer is A.

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Detailed Solution

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a)In (NH4)2[Ce(NO3)6] Ce oxidation state is +4

EC of Ce+4:[Xe]6s05d04f0, therefore n=0, hence magnetic moment =0

EC of Gd+3:[Xe]6s05d04f7, therefore n=7, hence magnetic moment =7.93 

EC of Eu+3:[Xe]6s05d04f6, therefore n=6, hence magnetic moment =6.92

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