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Q.

Arrange the following metal complex/compounds in the increasing order of spin only magnetic moment. Presume all the three, high spin system. (Atomic numbers Ce = 58, Gd = 64 and Eu = 63)

a) (NH4)2[Ce(NO3)6]
b) Gd(NO3)3
c) Eu(NO3)3

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a

c < a < b

b

a< b < c

c

a < c < b 
 

d

b < a < c

answer is A.

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Detailed Solution

a) (NH4)2[Ce(NO3)6]=Xe4f26s2 , Ce has +4 oxidation state  μ=0

b)GdNO33=Xe4f75d16s2Gd has +3 oxidation state,7 unpaired electrons;μ=7.9  

c)EuNO33  =Xe4f76s2 Eu has +3 oxidation state,6 unpaired electrons; μ=6.9

Hence, correct option is: (A) a < c < b  

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