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Q.

Aryl halides do not undergo nucleophilic substitution reactions under ordinary condition because
(1) Approach of nucleophile is retarded
(2) Carbon carrying halogen atom is sp3 hybridized
(3) The substrate molecule is destabilized due to resonance
(4) Partial double bond character between carbon and halogen

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a

2 and 4 only

b

1 and 4 only

c

2 and 3 only

d

2, 3 and 4 only

answer is B.

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Detailed Solution

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Aryl halides are less reactive towards nucleophilic substitution because of the partial double bond character of carbon halogen bond. It is also partly due to repulsion between π electron cloud of the benzene ring and the nucleophile 

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Aryl halides do not undergo nucleophilic substitution reactions under ordinary condition because(1) Approach of nucleophile is retarded(2) Carbon carrying halogen atom is sp3 hybridized(3) The substrate molecule is destabilized due to resonance(4) Partial double bond character between carbon and halogen