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Q.

As  +20  moles  H2O       Ain  20  moles  H2O;  ΔH=72kJ

As+40  moles  H2OAin  40  moles  H2O;  ΔH=  81kJ

Enthapy of dilution when a solution containing one mole of A in 20 moles H2O is diluted by adding 20 moles of H2O to it will be

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a

+9 kJ

b

-9 kJ

c

-153 kJ

d

+153 kJ

answer is B.

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Detailed Solution

Equation (2) – Equation (1)

  ΔH=9  kJ 

The reaction is exothermic with increase in dilution exothermic nature increases.

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