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Q.

As two atoms approach one another in space, the potential energy decreases and then increases as shown in the diagram below.

Question Image

To what are these two changes attributed?

[Note : p+ = proton, e- = electron]

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a

 

Decrease 

(from 0.40 to 0.15 nm) 

increase

 (from 0.15 to 0 mm)

(c)decreased p+ p+ repulsionincreased e- e-repulsion

b

 

Decrease 

(from 0.40 to 0.15 nm) 

increase

 (from 0.15 to 0 mm)

 (b)increased p+ e- attraction increased e- e- repulsion

c

 

Decrease 

(from 0.40 to 0.15 nm) 

increase

 (from 0.15 to 0 mm)

(a)increased p+ e- attraction increased p+ p+ repulsion

d

 

Decrease 

(from 0.40 to 0.15 nm) 

increase

 (from 0.15 to 0 mm)

(d)decreased p+ e-repulsionincreased p+ p+repulsion

answer is A.

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Detailed Solution

The strong attraction of each shared electron to both nuclei stabilizes the system, and the potential energy decreases as the bond distance decreases. If the atoms continue to approach each other, the positive charges in the two nuclei begin to repel each other, and the potential energy increases.

 

Decrease 

(from 0.40 to 0.15 nm) 

increase

 (from 0.15 to 0 mm)

(a)increased p+ e- attraction increased p+ p+ repulsion

Thus, the correct option is A.

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