Q.

Assertion   :  Azeotropic mixtures are formed only by

                    non-ideal solutions and they may have

                   boiling points either greater than both the

                   components or less than both the

                   components.

Reason   :   The composition of the vapour phase is

                   same as that of the liquid phase of an

                    azeotropic mixture.

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a

If both assertion and reason are true and the reason is

the correct explanation of the assertion. 

b

If both assertion and reason are true but reason is not

the correct explanation of the assertio

c

If assertion is true but reason is false.

d

If the assertion and reason both are false.

answer is B.

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Detailed Solution

Non-ideal solutions with positive deviation i.e., having more vapour pressure than expected, boil at lower temperature while those with negative deviation boil at higher temperature than those of the components. 

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