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Q.

Assertion : When aniline is subjected to nitration by conc HNO3 & H2SO4 meta nitro aniline is formed in considerable amount.

Reason : NH2 is o/p directing but ring deactivating group.

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a

Assertion is incorrect, reason is correct

b

Assertion is correct, reason is correct, reason is not a correct explanation for assertion.

c

Assertion is correct, reason is incorrect

answer is C.

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Detailed Solution

NH2 group ortho-para directing and activate ring towards electrophilic substitutions because this group stabilizes the arenium ion.

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