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Q.

Assertion (A):- Solubility of n-alcohol in water decreases with increase in molecular weight. 
Reason (R):- The reactive proportion of the hydrocarbon part in alcohols increases with increasing molecular weight which permits enhanced hydrogen bonding with water.

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a

A is correct R is not correct

b

Both  A  &  R are correct and R is not the correct explanation of A  

c

Both A  &  R are correct and R is correct explanation of A

d

A is not correct R is correct

answer is C.

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Detailed Solution

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The reactive proportion of the hydrocarbon part in alcohols increases with increasing molecular weight which increases hydrophobic repulsion.

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