Q.

Assertion (A)          : The first ionization energy of Be is greater than that of B.

Reason (R) : 2PElectrons are more loosely held than 2S electrons.

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a

Both A and R are correct and R is the correct explanation of A.

b

Both A and R are correct but R is not the correct explanation of A.

c

A is correct, R is incorrect.

d

A is incorrect, R is correct.

answer is A.

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Detailed Solution

Assertion: It is fact that first ionization energy of Be is greater than that of B because the electron has to be removed from the more stable  2S2 half –filled  orbital than the electron from  2p1 incompletely filled  orbital of B.

Reason: R  is correct ,and the correct explanation of A. Actually the ionisation energy depends on the  penetration  power of the orbitals , the order of penetration power of orbitals is s>p>d>fTherefore 2pElectrons are more loosely held than 2selectrons.

            2p Electrons are more loosely held than 2s 2S electrons.

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