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Q.

Assertion (A) : Electrolysis of NaCl solution gives chlorine at anode instead of oxygen

Reason (R) : Formation of oxygen at anode requires over potential

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a

Both ‘A’ and ‘R’ are true and ‘R’ is the correct explanation of ‘A’

b

Both ‘A’ and ‘R’ are true and ‘R’ is not the correct explanation of ‘A’

c

‘A’ is true but ‘R’ is false

d

‘A’ is false but ‘R’ is true

answer is A.

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Detailed Solution

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In the electrolysis of NaCl solution, chlorine is produced at anode instead of 02. The two half-cell reactions are:
2Cl-Cl2 +2e- ,E0=1.36v 2H2O O2(g) +4H+ +4e- ,E0=1.23v
Lower value of E Cell is preferred but due to overvoltage chlorine is liberated at anode.so Both ‘A’ and ‘R’ are true and ‘R’ is the correct explanation of ‘A’

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