Q.

Assertion (A) : The bond energy of H2molecule is greater than HCl molecule.

Reason (R) : The bond energy in the overlapping between 1s and 1ssub shells of H2is greater than that of 3p and Question Image sub shells of HCl.

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a

Both A and R are correct and R is the correct explanation of A.

b

A is incorrect, R is correct.

c

A is correct, R is incorrect.

d

Both A and R are correct but R is not the correct explanation of A.

answer is A.

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Detailed Solution

The bond energy of H2molecule is greater than HCl molecule.  Due to s-orbital’s two hydrogen atoms is close to the nucleus then the bond length is low.  But p-orbital of chlorine far to the nucleus then the bond length is high in HCl.  So the bond energy of  H2 is greater than HCl. 

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Assertion (A) : The bond energy of H2molecule is greater than HCl molecule.Reason (R) : The bond energy in the overlapping between 1s and 1ssub shells of H2is greater than that of 3p and sub shells of HCl.