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Q.

Assertion (A) :Addition of (NH4)2CO3  to an  aqueous  solution of BaCl2  in the presence of NH4OH  precipitates BaCO3  
Reason (R) :  Ba(OH)2  is soluble in water 

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a

Assertion is correct and Reason is incorrect

b

Assertion and Reason both are correct statements and Reason is the correct explanation of the Assertion 

c

Assertion and Reason both are correct statements but Reason is not the correct explanation of the Assertion

d

Both Assertion and Reason are incorrect

answer is B.

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Detailed Solution

Barium comes under group V in cation analysis. Addition of  (NH4)2CO3 to an aqueous solution of  BaCl2  in the  presence  of NH4Cl   and  NH4OH precipitates BaCO3  
 

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Assertion (A) :Addition of (NH4)2CO3  to an  aqueous  solution of BaCl2  in the presence of NH4OH  precipitates BaCO3  Reason (R) :  Ba(OH)2  is soluble in water