Q.

Assertion (A): Aniline cannot be prepared by Gabriel phthalimide synthesis.

Reason (R): NH2  group in aniline is highly activating towards electrophilic substitution.

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a

 Both A and R are false

b

 A is true but R is false

c

 Both A and R true, and R is correct explanation of A

d

Both A and R are true but R is not the correct explanation of A

answer is B.

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Detailed Solution

 C6H5Cl  is non reactive towards nucleophilic substitution    

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Assertion (A): Aniline cannot be prepared by Gabriel phthalimide synthesis.Reason (R): −NH2  group in aniline is highly activating towards electrophilic substitution.