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Q.

Assertion (A): Aniline does not undergo friedel craft alkylation and acylation

Reason (R) : Aniline forms salt with anhydrous AlCl3 (lewis acid) which is used as catalyst in friedel craft reaction

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a

Both Assertion and reason are correct but reason is not correct explanation

b

Assertion is correct but reason is wrong

c

Both assertion and reason are wrong

d

Both assertion and reason are correct and reason is correct explanation of assertion

answer is A.

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Detailed Solution

Reaction between aniline and AlCl3,

Ph-NH2AlCl3Ph-NH2AlCl3   +-

So, during the reaction  -NH2 group of aniline reacts with  AlCl3 to give salt. This is the reason why aniline does not undergo Friedel-Crafts reaction.

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