Q.

Assertion (A): Benzene diazonium chloride does not give Lassaigne's test for nitrogen. 

Reason (R): Nitrogen is lost as N2 gas on heating.

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a

(A) is true but (R) is false

b

Both (A) and (R) are true and (R) is the correct explanation of (A)

c

Both (A) and (R) are false

d

Both (A) and (R) are true and (R) is not the correct explanation of (A)

answer is A.

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Detailed Solution

Lassaigne's test is also known as the sodium fusion test. It is used in the elemental analysis of organic compounds.

Organic compound is fused with sodium and the carbon and nitrogen present in the compound form NaCN which is used in the test.

Benzene diazonium chloride doesn't form NaCN as it loses N2 gas on heating.

Thus, both assertion and reason are true and reason is the correct explanation of assertion

Hence, option (A) is correct.

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Assertion (A): Benzene diazonium chloride does not give Lassaigne's test for nitrogen. Reason (R): Nitrogen is lost as N2 gas on heating.