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Q.

Assertion (A) Carboxylic acids are higher boiling liquids than aldehydes, ketones and even alcohols of comparable molecular masses.

Reason (R) : More extensive association of carboxylic acid molecules occur through intermolecular hydrogen bonding.

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a

If both (A) and (R) are true and (R) is not the correct explanation of (A) 

 

b

If both (A) and (R) are false

c

If both (A) and (R) are true and (R) is the correct explanation of (A) 

 

d

If (A) is true but (R) is false 

 

answer is A.

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Detailed Solution

Carboxylic acids have higher boiling point than aldehydes, ketones & even alcohols of comparable molecular masses because of more extensive association of carboxylic acid molecules occur through intermolecular hydrogen bonding

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Assertion (A) Carboxylic acids are higher boiling liquids than aldehydes, ketones and even alcohols of comparable molecular masses.Reason (R) : More extensive association of carboxylic acid molecules occur through intermolecular hydrogen bonding.