Q.

Assertion (A) : CoNH363+ is an inner orbital complex
Reason (R) :  NH3 is strong ligand and produces strong field causing greater splitting of ‘d’ orbitals i.e. Δ0>P. (Where Δ0 is magnitude of crystal field splitting & P is pairing energy)

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a

Both A and R are true and R is the correct explanation of A

b

Both A and R are true and R is not the correct explanation of A

c

A is correct but R is not correct

d

A is not correct but R is correct

answer is A.

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Detailed Solution

CoNH363+ is an inner orbital complex.NH3 is strong ligand and produces strong field causing greater splitting of ‘d’ orbitals i.e. Δ0>P. (Where Δ0 is magnitude of crystal field splitting & P is pairing energy)

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