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Q.

Assertion (A): During diazotization, excess of HCl is used with NaNO2

Reason (R): Excess of HCl prevents the hydrolysis of diazonium salt.

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a

Both (A) and (R) are true and (R) is the correct explanation of (A)

b

Both (A) and (R) are true and (R) is not the correct explanation of (A)

c

 (A) is true but (R) is false

d

Both (A) and (R) are false

answer is C.

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Detailed Solution

Diazotization reaction,                                 

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In the diazotization reaction, to avoid the azo coupling we use HCl in excess.

So, to suppress the concentration of free aniline available for coupling excess of HCl is used in diazotization reactions.

Thus, the assertion is true but the reason is false.

 

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