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Q.

Assertion (A) : Free radical chlorination of n – butane gives 72% of 2 – chlorobutane and 28% of 1 – chlororbutane though it has six primary and four secondary hydrogen atoms
Reason (R) : A secondary hydrogen is substituted more easily than the primary hydrogen atoms

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a

Both A and R are true and R is not correct explanation of A

b

A is true but R is false

c

Both A and R are false

d

Both A  and R are true and R is correct explanation of A

answer is A.

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Detailed Solution

During free radical substitution of ‘H’ in alkane with halogen, the order of reactivity of 
 halogen with primary, secondary and teritiary hydrogen is 1 : 3.5 : 5 respectively

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