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Q.

Assertion (A): Gabriel phthalimide synthesis can't be used for the preparation of aromatic primary amines.

Reason (R): The C-X bond in aryl halides possess partial double bond character and hence X-can't be replaced by phthalimide ion.

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a

(A) is true but (R) is false

b

Both (A) and (R) are true and (R) is the correct explanation of (A)

c

Both (A) and (R) are false

d

Both (A) and (R) are true and (R) is not the correct explanation of (A)

answer is A.

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Detailed Solution

The Gabriel Synthesis of amines is the reaction in which primary halides are converted into primary amines via SN2 reaction.

It is used for the preparation of primary amines only.

Now,

The C-X bond present in haloarenes are difficult to break due to its partial double bond character.

Hence, option (A) is correct.

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