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Q.

Assertion (A): H2S has higher boiling point than H2O.
Reason (R): Molecular mass of H2S is more than H2O.

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a

A are R are true, R is the correct explanation of A 

b

A and R are true, but R is not the correct explanation of A 

c

A is false but R is true

d

A is true but R is false

answer is D.

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Detailed Solution

Water forms strong intermolecular hydrogen bonding. Hydrogen sulphide does not. As we know, stronger the intermolecular forces, higher will be boiling point. Hence, water has higher boiling point over hydrogen sulfide.

Molecular mass of H2S (34) is more than H2O (18).

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Assertion (A): H2S has higher boiling point than H2O.Reason (R): Molecular mass of H2S is more than H2O.