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Q.

Assertion (A): In gaseous state 3° - amines are more basic than 1° and 2° - amines. 

Reason (R): In gas phase basic strength depends only on inductive effect.

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a

Both (A) and (R) are true and (R) is the correct explanation of (A)

b

Both (A) and (R) are true and (R) is not the correct explanation of (A)

c

(A) is true but (R) is false

d

Both (A) and (R) are false

answer is A.

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Detailed Solution

The basicity of amines depends on the ease of the nitrogen atom to donate its lone pair of electrons.

For gaseous state,

Basicity of amines α Inductive effect

Order of inductive effect is,

3° amines >2° amines >1° amines

Therefore, order of basicity is,

3° amines >2° amines >1° amines

Thus, both assertion and reason are true and reason is the correct explanation of assertion.

Hence, option (A) is correct.

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