Q.

Assertion (A): In the addition of HBr to propene, isopropyl bromide is major product and n-propyl bromide is minor product.

Reason (R): Isopropyl carbonium ion is more stable than n - propyl carbonium ion.

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a

Both A and R are true and R is the correct explanation of A

b

A is false but R is true

c

Both A and R are true and R is not the correct explanation of A

d

A is true but R is false

answer is A.

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Detailed Solution

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The products above formed are if the reaction takes place in absence of peroxides, Such addition reactions are governed by an empirical rule, called Markovnikov rule. 

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