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Q.

Assertion (A) : In the bromination of phenol in CS2, a Lewis acid is not required.
Reason (R) : In this reaction phenol it self acts as Lewis acid.

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a

Both A and R are correct, R is not the correct explanation to A

b

Both A and R are correct, R is the correct explanation to A

c

A is true but R is false

d

A is false R is true

answer is C.

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Detailed Solution

During the bromination of any non polar substance like benzene, Lewis acid is used to polarize the attacking electrophile Br2.

But in case of highly polar phenol molecule, the oxygen atom present in the phenol molecule itself polarizes the incoming electrophile Br2​ to form ions. SO in this case no additional Lewis acid is required.

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Assertion (A) : In the bromination of phenol in CS2, a Lewis acid is not required.Reason (R) : In this reaction phenol it self acts as Lewis acid.