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Q.

Assertion(A): In the Lassaigne’s test for halogens, Lassaigne’s extract is boiled  with conc. HNO3  before testing for halogen. 
Reason (R) : Conc.  HNO3 decomposes  NaCN to HCN and Na2S  to  H2S and thus prevents their interference in the reaction

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a

Both(A) and (R)are true and (R) is the correct explanation of (A)

b

Both(A) and (R)are true and (R) is not the correct explanation if (A)
 

c

(A) is true but (R) is false
 

d

Both(A) and (R) are false

answer is A.

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Detailed Solution

L.E. is boiled with  HNO3 to expell HCN & H2S  if O.C contains N & S other wise they will interfere while testing with  AgNO3

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Assertion(A): In the Lassaigne’s test for halogens, Lassaigne’s extract is boiled  with conc. HNO3  before testing for halogen. Reason (R) : Conc.  HNO3 decomposes  NaCN to HCN and Na2S  to  H2S and thus prevents their interference in the reaction