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Q.

Assertion (A) : In weak electrolytes, the change in Λm with dilution is mainly due to increase in degree of dissociation
Reason (R) : At a given concentration of weak electrolyte the degree of dissociation α=Λ0mΛm

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a

Both A and R are true and R is the correct explanation of A

b

A is not correct but R is correct

c

A is correct but R is not correct

answer is D.

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Detailed Solution

According to Ostwald’s dilution law upon dilution the degree of ionisation of weak electrolyte increases. As no. of ions increases,  Λm also increase
According to kohlrausch law ΛmΛm0 in degree of dissosiation
 

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Assertion (A) : In weak electrolytes, the change in Λm with dilution is mainly due to increase in degree of dissociationReason (R) : At a given concentration of weak electrolyte the degree of dissociation α=Λ0mΛm