Q.

Assertion : A mixture of 100 ml of 0.2 M CH3COOH  and 100 ml of 0.1 M NaOH acts as buffer solution.
Reason : When  CH3COONa is  added to CH3COOH  solution pH of acetic acid solution increases due to common ion effect

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a

A is true R is false 

b

A is false, R is true 

c

Both A and R are correct R is not the correct explanation of A

d

Both A and R are correct R is the correct explanation of A

answer is B.

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Detailed Solution

W.acid>S.base so 100 ml of 0.2 M CH3COOH and 100 ml of 0.1 M NaOH mixture can act as buffer   when CH3COONa is added to CH3COOH solution [H+] decreases so pH increases

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Assertion : A mixture of 100 ml of 0.2 M CH3COOH  and 100 ml of 0.1 M NaOH acts as buffer solution.Reason : When  CH3COONa is  added to CH3COOH  solution pH of acetic acid solution increases due to common ion effect