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Q.

Assertion(A): Mono bromination of aniline is done by protecting the amine group by acylation and followed by hydrolysis of substituted amine.

Reason(R): Activating effect of -NHCOR is less than that of -NH2 Group.

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a

"A" true, "R" true and "R" explain "A".

b

"A" true, "R" true and "R" does nor explain "A".

c

"A" true, "R" false.

d

"A" false, "R"true.

answer is A.

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Detailed Solution

The lone pair of electrons in nitrogen of -NHCOR Interacts with oxygen atoms due to resonance, thus the activating effect of -NHCOR Is less than -NH2.

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Assertion(A): Mono bromination of aniline is done by protecting the amine group by acylation and followed by hydrolysis of substituted amine.Reason(R): Activating effect of -NHCOR is less than that of -NH2 Group.