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Q.

Assertion (A):  Nitration of chlorobenzene leads to the formation of m-nitrochlorobenzene 
Reason:  (R) :   NO2 group is a m-directing group. 

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a

Both A and R are true and R is not the correct explanation to A

b

Both A and R are true and R is the correct explanation to A

c

A is false but R is true

d

A is true but R is false

answer is D.

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Detailed Solution

Nitration of chlorobenzene leads to the formation of para and ortho-nitrochlorobenzene. This implies that A is false but R is true

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Assertion (A):  Nitration of chlorobenzene leads to the formation of m-nitrochlorobenzene Reason:  (R) :   NO2 group is a m-directing group.