Q.

Assertion (A): Primary amines with three (or) more carbon atoms are liquids and still higher ones are solids

Reason( R): Lower aliphatic amines are soluble in water because they can form hydrogen bonds with water molecules

Choose correct answer from the following

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a

If both (A) and (R) are true and (R) is the correct explanation of (A) 

 

b

If both (A) and (R) are true and (R) is not the correct explanation of (A) 

 

c

If (A) is true but (R) is false 

 

d

If both (A) and (R) are false

answer is B.

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Detailed Solution

Primary amines with three (or) more carbon atoms are liquids and still higher ones are solids. The lower amines forms hydrogen bonding with water because of less hydrophobic character but as the molecular mass of amines can increase, then hydrophobic character also increases-which ultimately decreases the hydrogen bonding with water.

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