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Q.

Assertion (A): The electronic configuration of Cr in the ground state is [Ar]4s13d5 instead of [Ar]4s23d4
Reason (R): The Average exchange energy associated with 4s13d5 configuration is more when compared to that of [Ar]4s23d4

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a

Both (A) and (R)  are true and (R) is the correct explanation of (A)

b

(A) is true but (R) is false

c

Both (A) and (R) are false

d

Both (A) and (R) are true and (R) is not the correct explanation of (A)

answer is A.

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Detailed Solution

However, we also know, half filled is more stable than partially filled orbitals. Also, 3d5 is more stable and less energy than 4s2 configuration. In case of Chromium, after the 4s2 3d4 configuration is attained, an electron from the 4s orbital jumps to 3d subshell because 3d5 is a much more stable configuration than 3d4. That's why final configuration for Chromium is 4s1 3d5 and not 3d4 4s2.

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