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Q.

Assertion (A) : [Ti(H2O)6]3+ is coloured while [Sc(H2O)6]3+ is colour less

Reason (R) : d-d transition are possible in [Sc(H2O)6]3+

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a

Both Assertion and Reason are correct but Reason is not correct explanation of the Assertion

b

Both Assertion and Reason are incorrect

c

Both Assertion and Reason are correct and the reason is the correct explanation of the Assertion.

d

Assertion is correct but Reason is incorrect

answer is C.

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Detailed Solution

[Sc(H2O)6]3+ has no unpaired electron in its d-subshell and thus d-d transition is not possible.

 [Ti(H2O)6]3+ has one unpaired electron in its d-subshell which gives rise to d-d transition.

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