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Q.

Assertion (A): Toluene on reaction with $B r_{2}$ in presence of sunlight gives a mixture of o-Bromo toluene and p-Bromo Toluene.
Reason(R): above reaction follows free radical substitution mechanism.

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a

Both A and R are true, and R is the correct explanation of A.

b

Both A and R are true, and R is not the correct explanation of A

c

A is true but R is false

d

A is false but R is true

answer is D.

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Detailed Solution

Toluene gives benzyl bromide on treating with $B r_{2}$ (1 mole) in presence of sunlight.

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Assertion (A): Toluene on reaction with Br2 in presence of sunlight gives a mixture of o-Bromo toluene and p-Bromo Toluene.Reason(R): above reaction follows free radical substitution mechanism.