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Q.

Assertion (A) : Z > 1 for H2 and He at all pressures at ordinary temperature.  

Reason (R) : Repulsive forces acting between them overcome the attracting forces at ordinary temperature.

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a

A and R are true and R is the correct explanation of A

b

A and R are true and R is not the correct explanation of A

c

A is true, R is false

d

Both A and R are false

answer is A.

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Detailed Solution

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So, the repulsive forces acting between them overcome the attracting forces and as a result, the actual volume of the gas becomes something more than the ideal value. - It is seen that Z is greater than one for hydrogen and helium at all pressure and it increases with increase in pressure.

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