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Q.

Assertion (A): Fe(CN)63 is weakly paramagnetic while Fe(CN)64 is diamagnetic.
Reason (R): Fe(CN)63 has +3 oxidation state while Fe(CN)64 has +2 oxidation state..
Select the most appropriate answer from the options given below:

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a

Both A and R are true and R is the correct explanation of A.

b

Both A and R are true but R is not the correct explanation of A.

c

A is false but R is true.

d

A is true but R is false.

answer is A.

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Detailed Solution

Oxidation state of Fe in potassium ferricyanide is +2, but in potassium ferrocyanide its oxidation state is +3.

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